3M AUSTRALIA PTY LIMITED 3M NEW ZEALAND LTD 950 Pacific Highway 250 Archers Road Pymble NSW 2073 Glenfield Auckland N.Z. Phone: 136 136 Phone: (9) 444 4760 24HR EMERGENCY: 1800 097 146 (Australia only). ============================================================================ MATERIAL SAFETY DATA SHEET ============================================================================ Document ID : 19-1905-9 Issue date : 23/11/2006 Version : 1.02 Supersedes date : 28/04/2004 Document status : Issued This MSDS has been prepared by 3M Australia Pty Ltd Toxicology Dept. ---------------------------------------------------------------------------- 1 PRODUCT AND COMPANY IDENTIFICATION ---------------------------------------------------------------------------- PRODUCT NAME 3M BRAND GLASS AND LAMINATE CLEANER DIVISION ZC - International Operations 3M Product ID AN-0105-5838-3, AN-0105-5839-1 RECOMMENDED USE: For industrial or professional use only. For cleaning glass and laminate surfaces. ---------------------------------------------------------------------------- 2 HAZARDS IDENTIFICATION ---------------------------------------------------------------------------- NOTE: C1 COMBUSTIBLE LIQUID. For more information refer AS 1940. NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. POISONS SCHEDULE Not applicable. Safety Codes and Phrases S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. ---------------------------------------------------------------------------- 3 COMPOSITION ---------------------------------------------------------------------------- Ingredient Name CAS number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 90 - 100 2-BUTOXYETHANOL 111-76-2 5 - 10 ETHANOLAMINE 141-43-5 0.5 - 1 3M BRAND GLASS AND LAMINATE CLEANER Page 2 of 7 . ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- 4 FIRST AID MEASURES ---------------------------------------------------------------------------- EYE CONTACT Get medical attention. Flush eyes with large amounts of water. SKIN CONTACT Wash affected area with soap and water. If signs/symptoms develop, get medical attention. INHALATION If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. IF SWALLOWED Do not induce vomiting. Get immediate medical attention. Give person two glasses of water. Never give anything by mouth to an unconscious person. ---------------------------------------------------------------------------- 5 FIRE FIGHTING MEASURES ---------------------------------------------------------------------------- SUITABLE EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). EXPOSURE HAZARDS DURING FIRE Closed containers exposed to heat from fire may build pressure and explode. Vapours may travel long distances along the ground or floor to an ignition source and flash back. FIRE FIGHTING PROCEDURES Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Turnout Gear) and a self-contained breathing apparatus (SCBA). Combustion Products from Fire Combustion Products from Fire are listed in Section 10, STABILITY AND REACTIVITY. ---------------------------------------------------------------------------- 6 ACCIDENTAL RELEASE MEASURES (SPILL) ---------------------------------------------------------------------------- Personal Precautions Observe precautions from other sections of this Material Safety Data Sheet. Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Ventilate area with fresh air. Contain spill. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a closed 3M BRAND GLASS AND LAMINATE CLEANER Page 3 of 7 . ---------------------------------------------------------------------------- container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. ---------------------------------------------------------------------------- 7 HANDLING AND STORAGE ---------------------------------------------------------------------------- Precautions for Safe Handling For industrial or professional use only. Avoid contact with oxidizing agents. Conditions for Safe Storage C1 COMBUSTIBLE LIQUID. For more information refer AS 1940. Incompatibility - Materials to Avoid Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. EXPLOSION AVOIDANCE Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Combustible liquid and vapour. Fire Avoidance Do not spray near flames or sources of ignition. ---------------------------------------------------------------------------- 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ---------------------------------------------------------------------------- 2-BUTOXYETHANOL (111-76-2) NATIONAL EXPOSURE STANDARDS: TWA: 20 ppm, 96.9 mg/m3. STEL: 50 ppm, 242 mg/m3. Overall exposure for this substance will be influenced by skin exposure, including mucous membranes and eyes, either by airborne or more particularly by direct contact with the substance. The presence of other solvents may alter skin absorption. ETHANOLAMINE (141-43-5) NATIONAL EXPOSURE STANDARDS: TWA 3ppm 7.5 mg/m3 STEL 6ppm 15 mg/m3 Special Information, Exposure/Protection The extent to which the following recommendations for exposure control and protection are observed should depend on the risk assessment undertaken for the specific conditions under which this product is used, including occupational hygiene measurements. Recommended Ventilation Use in a well-ventilated area. Eye Protection Avoid eye contact with vapour, spray, or mist. During operations in which eye exposure is likely, the following should be worn alone, or in combination, as appropriate: Indirect Vented goggles. Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance specifications of AS/NZS 1337. Hand Protection Gloves made from one of the following material(s) are recommended 3M BRAND GLASS AND LAMINATE CLEANER Page 4 of 7 . ---------------------------------------------------------------------------- (Gloves should be selected and used in accordance with AS/NZS 2161): Neoprene. Skin Protection Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing vapours, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapour filters. Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance specifications. For information about respirators, call 3M on 1800 024 464. Prevention of Accidental Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ---------------------------------------------------------------------------- 9 PHYSICAL/CHEMICAL PROPERTIES ---------------------------------------------------------------------------- Appearance and Odour Clear liquid; light floral odour pH 9 - 11 Boiling point 100 C Melting point 0 C Flash point > 65 C Autoignition temperature Not determined Vapour pressure Not determined Water Solubility Complete Specific gravity 0.998 Vapour density Not determined Evaporation rate Not determined Viscosity Not determined Flammable Limits - LEL Not determined Flammable Limits - UEL Not determined Percent Volatile Not determined 3M BRAND GLASS AND LAMINATE CLEANER Page 5 of 7 . ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- 10 STABILITY AND REACTIVITY ---------------------------------------------------------------------------- Stability Hazardous polymerisation will not occur. Stable. Materials to Avoid None known. Hazardous Decomposition Products Carbon Monoxide. Carbon Dioxide. ---------------------------------------------------------------------------- 11 TOXICOLOGICAL INFORMATION ---------------------------------------------------------------------------- Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms can include redness, swelling, pain, tearing and blurred or hazy vision. Effects from Skin Contact May be absorbed through skin and cause target organ effects. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion May be absorbed following ingestion and cause target organ effects. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhoea and vomiting. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, uncoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. ---------------------------------------------------------------------------- 12 ECOLOGICAL INFORMATION ---------------------------------------------------------------------------- Ecofate Data Not determined. ---------------------------------------------------------------------------- 13 DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------- Product as Sold Discharge spent solutions and small quantities (less than 20L) to a wastewater treatment system. As a disposal alternative, incinerate in an industrial or commercial facility. Special Instructions for Disposal Contact your local waste authority to determine suitable disposal methods. 3M BRAND GLASS AND LAMINATE CLEANER Page 6 of 7 . ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- 14 TRANSPORT INFORMATION ---------------------------------------------------------------------------- ADG (Road/Rail) --------------- UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED IATA (Airfreight) ----------------- UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED IMO (Seafreight) ---------------- UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED ---------------------------------------------------------------------------- 15 REGULATORY INFORMATION ---------------------------------------------------------------------------- Product Certifications AICS - Yes: Components checked 3M BRAND GLASS AND LAMINATE CLEANER Page 7 of 7 . ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- 16 OTHER INFORMATION ---------------------------------------------------------------------------- REASON FOR REISSUE This MSDS has been revised to include the combustible liquid statement. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet, which involves using the product, or otherwise that in accordance with instructions of use on product packaging is the responsibility of the user. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact the Snr Regulatory Services Officer on (02)9498-9287.